Let folk know than mate when your free and see if you can hook-up in here. Honestly I just log in and its luck of the draw. The chatroom has a good turnout most of the time and its new. I would never assume that the chatroom will be full and packed like a normal chatroom but is a place to get LIVE support, help and to hangout with the brotherhood.
If you want to talk to someone in particuler, such as dld than its best PM them and try arrange a time. Sometimes it can be impossible due to time zones but I'm sure that it can be worked around 9 times out of 10.